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Unexpected polymorphism during a catalyzed mechanochemical Knoevenagel condensation
The transformation of a base-catalyzed, mechano-assisted Knoevenagel condensation of mono-fluorinated benzaldehyde derivatives (p-, m-, o-benzaldehyde) with malonodinitrile was investigated in situ and in real time. Upon milling, the para-substituted product was found to crystallize initially into t...
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| Publicat a: | Beilstein J Org Chem |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6541349/ https://ncbi.nlm.nih.gov/pubmed/31164950 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.110 |
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