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Amides as Non-polymerizable Catalytic Adjuncts Enable the Ring-Opening Polymerization of Lactide With Ferrous Acetate Under Mild Conditions

Sn-based catalysts are effective in the ring-opening polymerization (ROP) but are toxic. Fe(OAc)(2) used as an alternative catalyst is suitable for the ROP of lactide only at higher temperatures (>170°C), associated with racemization. In the ROP of ester and amide group containing morpholinedione...

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Detalhes bibliográficos
Publicado no:Front Chem
Main Authors: Naolou, Toufik, Lendlein, Andreas, Neffe, Axel T.
Formato: Artigo
Idioma:Inglês
Publicado em: Frontiers Media S.A. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6535497/
https://ncbi.nlm.nih.gov/pubmed/31165060
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2019.00346
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