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Resonance promoted ring-opening metathesis polymerization of twisted amides

The living ring-opening metathesis polymerization (ROMP) of an unsaturated twisted amide using the third-generation Grubbs initiator is described. Unlike prior examples of ROMP monomers that rely on angular or steric strain for propagation, this system is driven by resonance destabilization of the a...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Xu, Mizhi, Bullard, Krista K., Nicely, Aja M., Gutekunst, Will R.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6993617/
https://ncbi.nlm.nih.gov/pubmed/32055341
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03602d
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