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Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

The α‐metallated ylides [Ph(3)P−C−Z](−)M(+) (with Z=SO(2)Tol or CN and M=Na or K) were used as versatile nucleophiles for the facile access to ylide‐substituted compounds. Halogenations, alkylations, carbonylations and functionalization reactions with main group element halides were easily accomplis...

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Foilsithe in:ChemistryOpen
Main Authors: Schwarz, Christopher, Scherpf, Thorsten, Rodstein, Ilja, Weismann, Julia, Feichtner, Kai‐Stephan, Gessner, Viktoria H.
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2019
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519319/
https://ncbi.nlm.nih.gov/pubmed/31123665
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201900094
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