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Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy(3)P‐C‐SO(2)Tol]M (M = Li, Na, K)

The preparation and isolation of the metalated ylides [Cy(3)PCSO(2)Tol]M ((Cy)1‐M) (with M = Li, Na, K) are reported. In contrast to its triphenylphosphonium analogue the synthesis of (Cy)1‐M revealed to be less straight forward. Synthetic routes to the phosphonium salt precursor (Cy)1‐H(2) via diff...

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Detalhes bibliográficos
Publicado no:Z Anorg Allg Chem
Main Authors: Darmandeh, Heidar, Scherpf, Thorsten, Feichtner, Kai‐Stephan, Schwarz, Christopher, Gessner, Viktoria H.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7386922/
https://ncbi.nlm.nih.gov/pubmed/32742041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/zaac.201900333
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