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Spectroscopic and Computational Evidence of Intramolecular Au(I)⋅⋅⋅H(+)−N Hydrogen Bonding

Despite substantial evidence of short Au⋅⋅⋅H−X contacts derived from a number of X‐ray structures of Au(I) compounds, the nature of Au(I)⋅⋅⋅H bonding in these systems has not been clearly understood. Herein, we present the first spectroscopic evidence for an intramolecular Au(I)⋅⋅⋅H(+)−N hydrogen bo...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Straka, Michal, Andris, Erik, Vícha, Jan, Růžička, Aleš, Roithová, Jana, Rulíšek, Lubomír
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519277/
https://ncbi.nlm.nih.gov/pubmed/30600866
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201811982
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