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Short Convergent Synthesis of the Mycolactone Core Through Lithiation–Borylation Homologations
Using iterative lithiation–borylation homologations, the mycolactone toxin core has been synthesized in 13 steps and 17 % overall yield. The rapid build‐up of molecular complexity, high convergence and high stereoselectivity are noteworthy features of this synthesis.
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| Pubblicato in: | Chemistry |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
WILEY‐VCH Verlag
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6519258/ https://ncbi.nlm.nih.gov/pubmed/26332797 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201503122 |
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