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Quantitative and Mechanistic Mechanochemistry in Ferrocene Dissociation
Ferrocene is classically regarded as being highly inert owing to the large dissociation energy of metal-cyclopentadienyl (Cp) bonds. We show that the Fe-Cp bond in ferrocene is the preferential site of mechanochemical scission in the pulsed ultrasonication of main-chain ferrocene-containing polybuta...
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| Publicado no: | ACS Macro Lett |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6516481/ https://ncbi.nlm.nih.gov/pubmed/31098336 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsmacrolett.8b00625 |
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