Quantitative and Mechanistic Mechanochemistry in Ferrocene Dissociation

Ferrocene is classically regarded as being highly inert owing to the large dissociation energy of metal-cyclopentadienyl (Cp) bonds. We show that the Fe-Cp bond in ferrocene is the preferential site of mechanochemical scission in the pulsed ultrasonication of main-chain ferrocene-containing polybuta...

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Udgivet i:ACS Macro Lett
Main Authors: Sha, Ye, Zhang, Yudi, Xu, Enhua, Wang, Zi, Zhu, Tianyu, Craig, Stephen L., Tang, Chuanbing
Format: Artigo
Sprog:Inglês
Udgivet: 2018
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6516481/
https://ncbi.nlm.nih.gov/pubmed/31098336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsmacrolett.8b00625
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