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Uncoupled activation and cyclization in catmint reductive terpenoid biosynthesis
Terpene synthases typically form complex molecular scaffolds by concerted activation and cyclization of linear starting materials in a single enzyme active site. Here we show that iridoid synthase, an atypical reductive terpene synthase, catalyzes the activation of its substrate 8-oxogeranial into a...
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| Publicado no: | Nat Chem Biol |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6513753/ https://ncbi.nlm.nih.gov/pubmed/30531909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41589-018-0185-2 |
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