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Cobalamin-Dependent Apparent Intramolecular Methyl Transfer for Biocatalytic Constitutional Isomerization of Catechol Monomethyl Ethers

[Image: see text] Isomerization is a fundamental reaction in chemistry. However, isomerization of phenyl methyl ethers has not been described yet. Using a cobalamin-dependent methyl transferase, a reversible shuttle concept was investigated for isomerization of catechol monomethyl ethers. The methyl...

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Foilsithe in:ACS Catal
Main Authors: Farnberger, Judith E., Hiebler, Katharina, Bierbaumer, Sarah, Skibar, Wolfgang, Zepeck, Ferdinand, Kroutil, Wolfgang
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Chemical Society 2019
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6503581/
https://ncbi.nlm.nih.gov/pubmed/31080689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b05072
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