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Enantioconvergent Biocatalytic Redox Isomerization

Alcohol dehydrogenases can act as powerful catalysts in the preparation of optically pure γ‐hydroxy‐δ‐lactones by means of an enantioconvergent dynamic redox isomerization of readily available Achmatowicz‐type pyranones. Imitating the traditionally metal‐mediated “borrowing hydrogen” approach to shu...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Liu, Yu‐Chang, Merten, Christian, Deska, Jan
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2018
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6468324/
https://ncbi.nlm.nih.gov/pubmed/29984878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804911
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