Nalaganje...
Biocatalytic Asymmetric Michael Additions of Nitromethane to α,β-Unsaturated Aldehydes via Enzyme-bound Iminium Ion Intermediates
[Image: see text] The enzyme 4-oxalocrotonate tautomerase (4-OT) exploits an N-terminal proline as main catalytic residue to facilitate several promiscuous C–C bond-forming reactions via enzyme-bound enamine intermediates. Here we show that the active site of this enzyme can give rise to further syn...
Shranjeno v:
| izdano v: | ACS Catal |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American
Chemical Society
2019
|
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6503466/ https://ncbi.nlm.nih.gov/pubmed/31080691 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00780 |
| Oznake: |
Označite
Brez oznak, prvi označite!
|