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Biocatalytic Asymmetric Michael Additions of Nitromethane to α,β-Unsaturated Aldehydes via Enzyme-bound Iminium Ion Intermediates
[Image: see text] The enzyme 4-oxalocrotonate tautomerase (4-OT) exploits an N-terminal proline as main catalytic residue to facilitate several promiscuous C–C bond-forming reactions via enzyme-bound enamine intermediates. Here we show that the active site of this enzyme can give rise to further syn...
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| Yayımlandı: | ACS Catal |
|---|---|
| Asıl Yazarlar: | , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
American
Chemical Society
2019
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| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6503466/ https://ncbi.nlm.nih.gov/pubmed/31080691 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00780 |
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