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Breaking the 1,2-HOPO barrier with a cyclen backbone for more efficient sensitization of Eu(iii) luminescence and unprecedented two-photon excitation properties

A cyclen backbone was utilized to study the effect of backbone rigidity on Eu(iii) luminescence sensitization using a 1,2-HOPO derivative and 2-thenoyltrifluoroacetonate (TTA) as chromophores. The restriction of molecular movement of Eu-Cy-HOPO brought about by the increased rigidity provided a tigh...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Dai, Lixiong, Lo, Wai-Sum, Gu, Yanjuan, Xiong, Qingwu, Wong, Ka-Leung, Kwok, Wai-Ming, Wong, Wing-Tak, Law, Ga-Lai
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6498141/
https://ncbi.nlm.nih.gov/pubmed/31123564
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00244h
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