Synthesis of a Conformationally Stable Atropisomeric Pair of Biphenyl Scaffold Containing Additional Stereogenic Centers

The synthesis of a new CF(3)-containing stereogenic atropisomeric pair of ortho-disubstituted biphenyl scaffold is presented. The atropisomers are surprisingly conformationally stable for isolation. X-ray structures show that their stability comes from an intramolecular hydrogen bond formation from...

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Bibliografische gegevens
Gepubliceerd in:Molecules
Hoofdauteurs: Yeung, Chi-Tung, Chan, Wesley Ting Kwok, Lo, Wai-Sum, Law, Ga-Lai, Wong, Wing-Tak
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: MDPI 2019
Onderwerpen:
Communication
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6385101/
https://ncbi.nlm.nih.gov/pubmed/30759758
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24030643
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