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Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes

We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Liu, Siyuan, Légaré, Marc-André, Hofmann, Alexander, Rempel, Anna, Hagspiel, Stephan, Braunschweig, Holger
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6495701/
https://ncbi.nlm.nih.gov/pubmed/31123576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00657e
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