Stereoinversion of Unactivated Alcohols by Tethered Sulfonamides

The direct, catalytic substitution of unactivated alcohols remains an undeveloped area of organic synthesis. Moreover, catalytic activation of this difficult electrophile with predictable stereo-outcomes presents an even more formidable challenge. Described herein is a simple iron-based catalyst sys...

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Udgivet i:Angew Chem Int Ed Engl
Main Authors: Marcyk, Paul T., Jefferies, Latisha R., AbuSalim, Deyaa I., Pink, Maren, Baik, Mu-Hyun, Cook, Silas P.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6489501/
https://ncbi.nlm.nih.gov/pubmed/30536739
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812894
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