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Copper Ligand and Anion Effects: Controlling the Kinetics of the Photoinitiated Copper(I) Catalyzed Azide—Alkyne Cycloaddition Polymerization

The kinetics of photoinduced copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) polymerizations were assessed as a function of copper(II) amine-based ligands. Copper(II) bromide ligated with 1,1,4,7,10,10-hexamethylenetetramine (HMTETA) exhibited the fastest kinetics in both Norrish type(I) and...

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Detalhes bibliográficos
Publicado no:Polym Chem
Main Authors: El-Zaatari, Bassil M., Cole, Shea M., Bischoff, Derek J., Kloxin, Christopher J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6483394/
https://ncbi.nlm.nih.gov/pubmed/31031838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C8PY01004H
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