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Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes
Metal carbenes, divalent carbon species, are versatile intermediates that enable novel synthetic pathways. These species exhibit either electrophilic or nucleophilic character, depending on the carbene and metal fragments. Although the metal carbene reactivity is regulated by the metal, the umpolung...
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| Publicado no: | iScience |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Elsevier
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6479018/ https://ncbi.nlm.nih.gov/pubmed/31015074 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.04.001 |
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