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Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes

Metal carbenes, divalent carbon species, are versatile intermediates that enable novel synthetic pathways. These species exhibit either electrophilic or nucleophilic character, depending on the carbene and metal fragments. Although the metal carbene reactivity is regulated by the metal, the umpolung...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:iScience
Main Authors: Zhang, Dan, Kang, Zhenghui, Liu, Junwen, Hu, Wenhao
Format: Artigo
Jezik:Inglês
Izdano: Elsevier 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6479018/
https://ncbi.nlm.nih.gov/pubmed/31015074
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.04.001
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