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Two-step Synthesis of Solasodine Pivalate from Diosgenin Pivalate
A two-step synthesis of solasodine pivalate from diosgenin pivalate is described. The key transformation involves the reaction of diosgenin pivalate with benzyl carbamate (CbzNH(2)) promoted by TMSOTf. During the reaction the F-ring of the spiroketal moiety opens up with a simultaneous introduction...
שמור ב:
| הוצא לאור ב: | Molecules |
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| Main Authors: | , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
MDPI
2019
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6471385/ https://ncbi.nlm.nih.gov/pubmed/30901960 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24061132 |
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