Synthesis and structure of palladium(II) complexes supported by bis-NHC pincer ligands for the electrochemical activation of CO(2)

A series of bis-NHC pincer complexes of palladium(II) have been prepared and characterized. These pyridyl-spaced dicarbene complexes ([(PDC(R))Pd(MeCN)](PF(6))(2)) were synthesized with substituents of varying steric bulk at the wingtip positions, which include R = methyl, ethyl, isopropyl, cyclohex...

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Udgivet i:Polyhedron
Main Authors: Andrade, Gabriel A., DiMeglio, John L., Guardino, Eric T., Yap, Glenn P.A., Rosenthal, Joel
Format: Artigo
Sprog:Inglês
Udgivet: 2017
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6457682/
https://ncbi.nlm.nih.gov/pubmed/30983680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2017.06.018
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