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Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis–NHC framework
The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDC(Mes))PdMe(2) towards CO(2) has been investigated. In the presence of trace H(2)O, this reaction yields the corresponding methyl bicarbonate complex (MDC(Mes))PdMe(O(2)COH), which goes on to give the corresponding κ(...
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| Hoofdauteurs: | , , |
|---|---|
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2012
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3443874/ https://ncbi.nlm.nih.gov/pubmed/22643651 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2dt30676j |
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