Key Mechanistic Features in Palladium-Catalyzed Methylcyclopropanation of Norbornenes With Vinyl Bromides: Insights From DFT Calculations

DFT calculations were performed to elucidate mechanistic details of an unusual palladium-catalyzed methylcyclopropanation from [2 + 1] cycloadditions of (Z)-2-bromovinylbenzene and endo-N-(p-tolyl)-norbornenesuccinimide. The reaction proceeds via oxidative addition (OA), intermolecular alkene insert...

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Detalhes bibliográficos
Publicado no:Front Chem
Main Authors: Ying, Fang, Zhang, Yutong, Xiang, Chuyue, Song, Zhijun, Xie, Hujun, Bao, Weiliang
Formato: Artigo
Idioma:Inglês
Publicado em: Frontiers Media S.A. 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6445852/
https://ncbi.nlm.nih.gov/pubmed/30972329
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2019.00169
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