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Stereochemical investigations on the biosynthesis of achiral (Z)-γ-bisabolene in Cryptosporangium arvum

A newly identified bacterial (Z)-γ-bisabolene synthase was used for investigating the cyclisation mechanism of the sesquiterpene. Since the stereoinformation of both chiral putative intermediates, nerolidyl diphosphate (NPP) and the bisabolyl cation, is lost during formation of the achiral product,...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Rinkel, Jan, Dickschat, Jeroen S
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6444425/
https://ncbi.nlm.nih.gov/pubmed/30992727
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.75
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