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Synthesis of (18)F-difluoromethylarenes using aryl boronic acids, ethyl bromofluoroacetate and [(18)F]fluoride

Herein, we report the radiosynthesis of (18)F-difluoromethylarenes via the assembly of three components, a boron reagent, ethyl bromofluoroacetate, and cyclotron-produced non-carrier added [(18)F]fluoride. The two key steps are a copper-catalysed cross-coupling reaction, and a Mn-mediated (18)F-fluo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Sap, Jeroen B. I., Wilson, Thomas C., Kee, Choon Wee, Straathof, Natan J. W., Ende, Christopher W. am, Mukherjee, Paramita, Zhang, Lei, Genicot, Christophe, Gouverneur, Véronique
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6429591/
https://ncbi.nlm.nih.gov/pubmed/30996907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05096a
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