Selective C–C bond formation from rhodium-catalyzed C–H activation reaction of 2-arylpyridines with 3-aryl-2H-azirines

A novel method for the synthesis of acylmethyl-substituted 2-arylpyridine derivatives using 3-aryl-2H-azirines was developed by exploring a prototype reaction using DFT-calculations and carrying out targeted experiments guided by the calculated mechanism. 2H-Azirine was initially hypothesized to rin...

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Vydáno v:Chem Sci
Hlavní autoři: Baek, Yonghyeon, Kim, Jinwoo, Hyunseok Kim, Jung, Seung Jin, Ryu, Ho, Kim, Suyeon, Son, Jeong-Yu, Um, Kyusik, Han, Sang Hoon, Seo, Hyung Jin, Heo, Juyoung, Lee, Kooyeon, Baik, Mu-Hyun, Lee, Phil Ho
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2019
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6419924/
https://ncbi.nlm.nih.gov/pubmed/30996984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05142a
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