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Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design
Enantio- and diastereoselective conjunctive cross-coupling of β-substituted alkenylboron “ate” complexes is studied. While β substitution shifts the chemoselectivity of the catalytic reaction in favor of the Suzuki-Miyaura product, use of a boronic ester ligand derived from acenaphthoquinone allows...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6414218/ https://ncbi.nlm.nih.gov/pubmed/30376317 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09909 |
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