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Frontier molecular orbital effects control the hole-catalyzed racemization of atropisomeric biaryls
Atropisomeric biaryl systems are privileged architectures used in asymmetric synthesis and pharmaceutical structures. We report that by simply removing a single-electron, the resistance of biaryls towards racemization is reduced dramatically. Even though the steric properties are unaltered, biaryl o...
Shranjeno v:
| izdano v: | Chem Sci |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6399675/ https://ncbi.nlm.nih.gov/pubmed/30931095 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05066j |
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