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Enantioconvergent Cross–Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes

Metal-catalyzed enantioconvergent cross-coupling reactions of alkyl electrophiles are emerging as a powerful tool in asymmetric synthesis. To date, high enantioselectivity has been limited to couplings of electrophiles that bear a directing group or a proximal p/π orbital. In this report, we demonst...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Schwarzwalder, Gregg M., Matier, Carson D., Fu, Gregory C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6399024/
https://ncbi.nlm.nih.gov/pubmed/30650228
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201814208
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