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A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives
The substitution reactions of [Rh(COD)(2)][BAr(F)(4)] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F(2)C(6)H(4) are shown to be an operationally simple method for the generation of...
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| Publicado no: | Dalton Trans |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6394201/ https://ncbi.nlm.nih.gov/pubmed/30729961 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt05049j |
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