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BF(3)-Promoted, Carbene-like, C–H Insertion Reactions of Benzynes
Boron trifluoride is observed to promote a variety of C–H insertion reactions of benzynes bearing pendant alkyl groups. Computations and various mechanistic studies indicate that BF(3) engages the strained π-bond to confer carbene-like character on the adjacent, non-coordinated benzyne carbon. This...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6386166/ https://ncbi.nlm.nih.gov/pubmed/30384597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b10206 |
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