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Benzyne Cascade Reactions via Benzoxetenonium Ions and their Rearrangements to o-Quinone Methides
A new thermal isomerization of polyynes is described. Benzyne intermediates substituted by a C(RR’)OR” substituent adjacent to one of the benzyne sp-hybridized carbons give rise to products in which the OR” moiety has migrated to the proximal benzyne carbon. This process likely proceeds via sequenti...
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| Veröffentlicht in: | Org Lett |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6742951/ https://ncbi.nlm.nih.gov/pubmed/30829492 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b00215 |
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