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[La(η(x)-B(x))La](–) (x = 7–9): a new class of inverse sandwich complexes

Despite the importance of bulk lanthanide borides, nanoclusters of lanthanide and boron have rarely been investigated. Here we show that lanthanide–boron binary clusters, La(2)B(x)(–), can form a new class of inverse-sandwich complexes, [Ln(η(x)-B(x))Ln](–) (x = 7–9). Joint experimental and theoreti...

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Publicat a:Chem Sci
Autors principals: Chen, Teng-Teng, Li, Wan-Lu, Li, Jun, Wang, Lai-Sheng
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6385817/
https://ncbi.nlm.nih.gov/pubmed/30881684
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05443f
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