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Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions

Functionalization of amide bond via the cleavage of a non-carbonyl, C-N σ bond remains under-investigated. In this work, a transition-metal-free single-electron transfer reaction has been developed for the C-N σ bond cleavage of N-acylazetidines using the electride derived from sodium dispersions an...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Li, Hengzhao, Lai, Zemin, Adijiang, Adila, Zhao, Hongye, An, Jie
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6384560/
https://ncbi.nlm.nih.gov/pubmed/30696043
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24030459
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