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Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions
Functionalization of amide bond via the cleavage of a non-carbonyl, C-N σ bond remains under-investigated. In this work, a transition-metal-free single-electron transfer reaction has been developed for the C-N σ bond cleavage of N-acylazetidines using the electride derived from sodium dispersions an...
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| 發表在: | Molecules |
|---|---|
| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
MDPI
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6384560/ https://ncbi.nlm.nih.gov/pubmed/30696043 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24030459 |
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