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Insights into base-free OsO(4)-catalyzed aminohydroxylations employing chiral ligands
Attempts to perform the OsO(4)-catalyzed enantioselective base-free aminohydroxylation of β,β-disubstituted enoates are described. Low yields and racemic products were obtained in the presence of standard chiral ligands, suggesting the occurrence of a “Second Cycle” process due to slow hydrolysis of...
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| Udgivet i: | Tetrahedron |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6374041/ https://ncbi.nlm.nih.gov/pubmed/30774161 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.01.018 |
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