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Ag(I)–C–H Activation Enables Near-Room-Temperature Direct α-Arylation of Benzo[b]thiophenes
[Image: see text] The first example of near-room-temperature α-arylation of benzo[b]thiophenes is reported. The discovery rests on the observation of a switch in α-/β-regioselectivity at different loadings of Pd(2)(dba)(3)·CHCl(3) in the coupling between benzo[b]thiophene and 4-iodotoluene. We show...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2018
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6370252/ https://ncbi.nlm.nih.gov/pubmed/29983049 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05361 |
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