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Methanesulfonyl-Polarized Halogen Bonding Enables Strong Halide Recognition in an Arylethynyl Anion Receptor

A 3,5-bis((2-iodophenyl)ethynyl)pyridinium scaffold was synthesized which introduces the use of methanesulfonyl withdrawing groups to polarize iodine halogen bonding units for anion binding. We investigate the capability of this receptor to bind halides in polar media, while further probing the stru...

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Bibliographic Details
Published in:Chem Commun (Camb)
Main Authors: Lohrman, Jessica A., Deng, Chun-Lin, Shear, Trevor A., Zakharov, Lev N., Haley, Michael M., Johnson, Darren W.
Format: Artigo
Language:Inglês
Published: 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6367007/
https://ncbi.nlm.nih.gov/pubmed/30680378
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc09251f
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