Methanesulfonyl-Polarized Halogen Bonding Enables Strong Halide Recognition in an Arylethynyl Anion Receptor

A 3,5-bis((2-iodophenyl)ethynyl)pyridinium scaffold was synthesized which introduces the use of methanesulfonyl withdrawing groups to polarize iodine halogen bonding units for anion binding. We investigate the capability of this receptor to bind halides in polar media, while further probing the stru...

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Udgivet i:Chem Commun (Camb)
Main Authors: Lohrman, Jessica A., Deng, Chun-Lin, Shear, Trevor A., Zakharov, Lev N., Haley, Michael M., Johnson, Darren W.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6367007/
https://ncbi.nlm.nih.gov/pubmed/30680378
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc09251f
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