Raising the Diversity of Ugi Reactions Through Selective Alkylations and Allylations of Ugi Adducts

We report here selective Tsuji-Trost type allylation of Ugi adducts using a strategy based on the enhanced nucleophilicity of amide dianions. Ugi adducts derived from aromatic aldehydes were easily allylated at their peptidyl position with allyl acetate in the presence of palladium catalysts. These...

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Argitaratua izan da:Front Chem
Egile Nagusiak: Zidan, Alaa, El-Naggar, Abeer M., Abd El-Sattar, Nour E. A., Ali, Ali Khalil, El Kaïm, Laurent
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Frontiers Media S.A. 2019
Gaiak:
Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6361783/
https://ncbi.nlm.nih.gov/pubmed/30761290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2019.00020
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