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Sulfonylation of 1,4‐Diazabicyclo[2.2.2]octane: Charge‐Transfer Complex Triggered C−N Bond Cleavage

A novel charge‐transfer complex triggered sulfonylation of 1,4‐diazabicyclo[2.2.2]octane (DABCO) with mild reaction conditions has been developed. The formation of a charge‐transfer complex between electron‐withdrawing (hetero)aryl sulfonyl chloride and DABCO allows the synthesis of N‐ethylated pipe...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Fu, Ying, Xu, Qin‐Shan, Li, Quan‐Zhou, Li, Ming‐Peng, Shi, Chun‐Zhao, Du, Zhengyin
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6350051/
https://ncbi.nlm.nih.gov/pubmed/30723657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201800251
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