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Crystal structures of 1,4-di­aza­bicyclo­[2.2.2]octan-1-ium 4-nitro­benzoate dihydrate and 1,4-di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(4-nitro­benzoate): the influence of solvent upon the stoichiometry of the formed salt

The 1:1 co-crystallization of 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO) with 4-nitro­benzoic acid in ethanol–water (3/1) gave the salt dihydrate C(6)H(13)N(2) (+)·C(7)H(4)NO(4) (−)·2H(2)O, (1), whereas from methanol, the salt C(6)H(14)N(2) (2+)·2C(7)H(4)NO(4) (−), (2), was isolated. In (1), the catio...

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Detalhes bibliográficos
Main Authors: Akhmad Aznan, Aina Mardia, Abdullah, Zanariah, Tiekink, Edward R. T.
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4120614/
https://ncbi.nlm.nih.gov/pubmed/25161500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536814011532
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