Strongly coloured thiocyanate frameworks with perovskite-analogue structures

We report the first examples of thiocyanate-based analogues of the cyanide Prussian blue compounds, M(III)[Bi(SCN)(6)], M = Fe, Cr, Sc. These compounds adopt the primitive cubic pcu topology and show strict cation order. Optical absorption measurements show these compounds have band gaps within the...

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Foilsithe in:Chem Sci
Main Authors: Cliffe, Matthew J., Keyzer, Evan N., Dunstan, Matthew T., Ahmad, Shahab, De Volder, Michael F. L., Deschler, Felix, Morris, Andrew J., Grey, Clare P.
Formáid: Artigo
Teanga:Inglês
Foilsithe: The Royal Society of Chemistry 2018
Ábhair:
Chemistry
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6345348/
https://ncbi.nlm.nih.gov/pubmed/30774873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04082f
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