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Strongly coloured thiocyanate frameworks with perovskite-analogue structures
We report the first examples of thiocyanate-based analogues of the cyanide Prussian blue compounds, M(III)[Bi(SCN)(6)], M = Fe, Cr, Sc. These compounds adopt the primitive cubic pcu topology and show strict cation order. Optical absorption measurements show these compounds have band gaps within the...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
The Royal Society of Chemistry
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6345348/ https://ncbi.nlm.nih.gov/pubmed/30774873 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04082f |
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