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Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation
1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr(iii) in a pincer complex. Two nitrate oxygens are removed to give the 17 valence electron octahedral complex (H(2)L)Cr(NO(3))(2)(NO). This is shown by a variety...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6335631/ https://ncbi.nlm.nih.gov/pubmed/30746094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02979b |
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