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Stereoselective Formation of Substituted 1,3-Dioxolanes through a Three-Component Assembly during the Oxidation of Alkenes with Hypervalent Iodine(III)

Stereoselective formation of substituted 1,3-dioxolanes was achieved through an assembly of three components: alkene, carboxylic acid and silyl enol ether. The reaction proceeded via stereospecific generation of a 1,3-dioxolan-2-yl cation intermediate during oxidation of alkene substrates with hyper...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Shimogaki, Mio, Fujita, Morifumi, Sugimura, Takashi
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6332268/
https://ncbi.nlm.nih.gov/pubmed/26393548
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules200917041
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