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Mechanistic investigation into the C(sp(3))–H acetoxylation of morpholinones
The study of a selective palladium(ii)-catalyzed C(sp(3))–H acetoxylation reaction on a class of cyclic alkyl amines is reported. Computational modelling and kinetic studies were used to provide support for a mechanism involving selective C–O bond formation from a γ-aminoalkyl-Pd(iv) intermediate. T...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6331033/ https://ncbi.nlm.nih.gov/pubmed/30713620 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03434f |
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