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Structure Revision of Poecillastrin C and the Absolute Configuration of the β‑Hydroxyaspartic Acid Residue
The planar structure of poecillastrin C (1) was revised through selective reduction of the ester carbon. The absolute configuration of the β-hydroxyaspartic acid (OHAsp) residue was determined to be D-threo by Marfey’s analysis. The acid hydrolysate of the reduction product of 1 liberated (2R,3R)-2-...
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| Pubblicato in: | Org Lett |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6325643/ https://ncbi.nlm.nih.gov/pubmed/28956931 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02835 |
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