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pH effects on the electrochemical reduction of CO((2)) towards C(2) products on stepped copper

We present a microkinetic model for CO((2)) reduction (CO((2))R) on Cu(211) towards C(2) products, based on energetics estimated from an explicit solvent model. We show that the differences in both Tafel slopes and pH dependence for C(1) vs C(2) activity arise from differences in their multi-step me...

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Bibliografski detalji
Izdano u:Nat Commun
Glavni autori: Liu, Xinyan, Schlexer, Philomena, Xiao, Jianping, Ji, Yongfei, Wang, Lei, Sandberg, Robert B., Tang, Michael, Brown, Kristopher S., Peng, Hongjie, Ringe, Stefan, Hahn, Christopher, Jaramillo, Thomas F., Nørskov, Jens K., Chan, Karen
Format: Artigo
Jezik:Inglês
Izdano: Nature Publishing Group UK 2019
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6318338/
https://ncbi.nlm.nih.gov/pubmed/30604776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07970-9
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