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Atomically precise Au(144)(SR)(60) nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects

For two decades, Au(144)(SR)(60) has been one of the most studied and used thiolate (SR) protected gold nanoclusters. In many ways, however, it proved to be a challenging and elusive case, also because of the difficulties in solving its structure by single-crystal X-ray crystallography. We used very...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
الحاوية / القاعدة:Chem Sci
المؤلفون الرئيسيون: Dainese, Tiziano, Agrachev, Mikhail, Antonello, Sabrina, Badocco, Denis, Black, David M., Fortunelli, Alessandro, Gascón, José A., Stener, Mauro, Venzo, Alfonso, Whetten, Robert L., Maran, Flavio
التنسيق: Artigo
اللغة:Inglês
منشور في: Royal Society of Chemistry 2018
الموضوعات:
الوصول للمادة أونلاين:https://ncbi.nlm.nih.gov/pmc/articles/PMC6301266/
https://ncbi.nlm.nih.gov/pubmed/30647884
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04092c
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